Add lone pairs to the lewis structures of these polyhalide ions

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Add lone pairs to these Lewis structures of polyha

Answer

General guidance

Concepts and reason
The problem is based on the concept of Lewis structure.

Lewis structure is the electron dot structure and represents the electron distribution in the atom. Lewis structure generally follows the octet rule.

Fundamentals

The electron distribution in the atom is represented by Lewis structure. The electrons in the outer shell are known as valence electrons. To complete the octet of the atom, valence shell should have 8 electrons. For the Lewis structure, the total number of valence electrons and number of electrons needed to complete the octet of the atom are counted. In the molecule, the total number of bonds in the molecule is counted and the skeletal structure of the compound is drawn. The total electrons are counted in the bond and the remaining electrons are added to the atom such that the octet of each atom is complete. The electrons which are not bonded to the bond are the non-bonding electrons and are termed as the lone pairs.

Step-by-step

Step 1 of 3

Part 1

Count the total number of valence electronsп.
Псть in [CIF,Jas follows:

= (x7)+(2x7)
+1
Пск
Тсть
22

The total number of valence electronsп.
Псть in [CIF,Jare 22 electrons.

Consider the skeletal structure of [CIF,Jas follows:

F CIF
Cl-

The skeletal structure has 4 electrons. 18 valence electrons are remaining. Give 6 electrons to each atom of CIand F. Draw the Lewis structure of [CIF,Jas follows:

Cl

Part 1

The Lewis structure for [CIF,Jwith lone pairs is as follows:

Cl

The compound [CIF,Jhas 22 electrons. Two bonds are present in the compound which counts as 4 electrons. The remaining 18 electrons are distributed to the Chlorine (Cl) and Fluorine (F) atoms such that each atom of CIand Fhas 6 non- bonding electrons. The compound [CIF,Jdo not follow the octet rule.

Step 2 of 3

Part 2

Count the total number of valence electronsп.
Iст, in [CIF,as follows:

Псть 3 (1x7) + (2х7)-1
20

The total number of valence electronsп.
Iст, in [CIF,are 20 electrons.

Consider the skeletal structure of [CIF,as follows:

F CIF
Cl-

The skeletal structure has 4 electrons. 16 valence electrons are remaining. Give 6 electrons to each atom of CIand F. Therefore, the octet of CIand Fis complete. Draw the Lewis structure of [CIF,as follows:

Part 2

The Lewis structure for [CIF,with lone pairs is as follows:

The compound has 20 electrons. Two bonds are present in the compound which counts as 4 electrons. The remaining 16 electrons are distributed to the Chlorine (Cl) and Fluorine (F) atoms such that each atom ofFhas 6 non- bonding electrons and CIatom has 4 non- bonding electrons. The compound follow the octet rule.

Step 3 of 3

Part 3

Count the total number of valence electronsп.
IсE, in [CIF,Jas follows:

(1x7)+(4x7)
Пст
=36

The total number of valence electronsп.
IсE, in [CIF,Jare 36 electrons.

Consider the skeletal structure of [CIF,Jas follows:

F
СCІ;
FA
F

The skeletal structure has 8 electrons. 28 valence electrons are remaining. Give 4 electrons to CIand 6 electrons to each atom of F. Draw the Lewis structure of [CIF,Jas follows:

ci.
|:F.

Part 3

The Lewis structure of [CIF,Jwith lone pairs is as follows:

ci.
|:F.

The compound has 36 electrons. Four bonds are present in the compound which counts as 8 electrons. The remaining 28 electrons are distributed to the Chlorine (Cl) and Fluorine (F) atoms such that each atom of Fhas 6 non- bonding electrons and CIatom has 46 non- bonding electrons. The compound do not follow the octet rule.

Answer

Part 1

The Lewis structure for [CIF,Jwith lone pairs is as follows:

Cl

Part 2

The Lewis structure for [CIF,with lone pairs is as follows:

Part 3

The Lewis structure of [CIF,Jwith lone pairs is as follows:

ci.
|:F.

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