Name the monosaccharides in the images by placing the appropriate terms.

Name the following monosaccharides by placing the appropriate
terms
Name the following monosaccharides by placing the

Answer

General guidance

Concepts and reason

The concept used to solve this problem is to locate the anomeric carbon in the given structure and then name the compound using the configuration.

If the given monosaccharide, –OH group and -CH,OH group are trans to each other, then it is called as anomer. Similarly, if –OH group and -CH,OH group are cis to each other, then it is called as anomer.

If the -CH,OHgroup is drawn up, then it is known as D-sugar. If the -CH,OHgroup is drawn down, then it is known as L-sugar.

Fundamentals

Anomers are the two structural forms of same molecule which differentiate from each other only in the direction of the OH (hydroxyl) group present at the hemiacetal carbon.

Six-membered ring containing an oxygen atom is known as pyranose ring. Similarly, the five-membered ring containing an oxygen atom is known as furanose ring.

Step-by-step

Step 1 of 3

The structure is as follows:

СН,ОН
он
—о
он
B anomer
ОН
он

This is a six-membered ring, so it is a pyranose.

The name of the monosaccharide is B-D-galactopyranose.

Here, the –OH group and -CH,OH group are cis to each other, so it is a anomer. The -CH,OHis facing towards up, so it is D. Thus, the name of the monosaccharide is B-D-galactopyranose.

Step 2 of 3

The structure is as follows:

он,
СН2ОН ОН
B anomer
ОН
ОН

This is a six-membered ring, so it is a pyranose.

The name of the monosaccharide is B-L-glucopyranose.

Here, the –OH group and -CH,OH group are cis to each other, so it is a anomer. The -CH,OHis facing towards down, so it is L. Thus, the name of the monosaccharide isB-L-glucopyranose.

Step 3 of 3

The structure is as follows:

CH OH
OHB anomer
СН,ОН
OH

This is a five-membered ring, so it is a furanose.

The name of the monosaccharide is B-D-fructofuranose.

Here, the –OH group and -CH,OH group are cis to each other, so it is a anomer. The -CH,OHis facing towards up, so it is D. Thus, the name of the monosaccharide isB-D-fructofuranose.

Answer

The name of the monosaccharide is B-D-galactopyranose.

The name of the monosaccharide is B-L-glucopyranose.

The name of the monosaccharide is B-D-fructofuranose.

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