What is the pH of a 0.0100 M sodium benzoate solution? Kb for the benzoate anion (C7H5O2–) = 1.5 × 10–10?

2 Answers

  • Ph Of Sodium Benzoate

  • Let B^-1 = C7H5O2^-1

    B^-1 + H2O <---> BH + OH^-1

    Kb = [BH][OH-] / [B^-1]

    [BH] = [OH^-1]

    1.5x10^-10 = [OH-]^2 / ([B^-1] - [OH^-1])

    Assume [OH-] << [B^-]

    1.5x10^-10 = [OH-]^2 /[B-]

    [OH-]^2 = 1.5x10^-10 x 0.0100

    [OH-] = 1.22x10^-6

    pOH = 5.91

    pH = 14.00 - 5.91 = 8.09

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